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  • What are the types of bond orders? - Matter Modeling Stack Exchange
    Laplacian Bond Order This method is an extension of the QTAIM (Quantum Theory of Atoms In Molecules) concept of using the Laplacian of the electron density ∇2ρ ∇ 2 ρ to characterize bonding Standard QTAIM just uses the value of ∇2ρ ∇ 2 ρ at bond critical points (minimum electron density along the bond, max along orthogonal directions), but these values are unintuitive and often
  • Lost atoms in LAMMPS - Matter Modeling Stack Exchange
    HI @Magic_Number, after running with more recorded timestep, I think the main reason is because the molecule pass through zlo and have atom deleted, as result, the bond connecting that atom is lost But I know having a fixed z boundary is possible to run because that's what I found from several lammps papers
  • Bond length from infrared spectra? - Matter Modeling Stack Exchange
    If you know the bond lengths of few such compounds, you can derive a very accurate linear correlation between the bond length and the frequency So while you can't directly predict bond lengths from IR alone, you can likely develop a correlation between a particular IR frequency and bond length for a series of related compounds
  • Generate structure using atomic coordinates - Matter Modeling Stack . . .
    10 To understand the new coordinates after altering the bond length of the C-O bonds you can use the below approach: Let us first visualize the positions of all the atoms before and after altering the bond length: The atoms with * are the atoms at the new coordinates after bond altering So imagine a vector from the O atom to the C atom
  • proteins - From a PDB file, how may I know which atoms have bonds . . .
    A bond is present when the distance between two atoms is lower than the sum of the Van der Waals radii of the two atoms Van der Waals radii are typically looked up from a preexisting table, not calculated We can find such tables in chemical reference books or online For instance, here is a link that supplies the following Van der Waals radii
  • Maximum bond length in Vesta - Matter Modeling Stack Exchange
    I need some cutoff radii to count bonds between different atoms in my system When a cif file is opened in Vesta, there are some default values of min and max bond lengths between two atomic speci
  • Scanning two bond lengths G-16 - Matter Modeling Stack Exchange
    When you are scanning two bond lengths in Gaussian, you step once through the first bond scan, and complete stepping through the second bond scan For example, consider the case where you are scanning the bond lengths of C-Cl and C-H in chloromethane The code will first increment the bond length of C-Cl, and will then scan the C-H bond while keeping C-Cl bond constant This will result in a
  • density functional theory - How to calculate homolytic bond . . .
    An experimental colleague asked me how hard it would be to calculate homolytic bond-dissociation energies for different phosphonates which are involved in a Hydrophosphination The compounds include




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